You can search for a work contact from your Exchange ActiveSync account, and then copy it on HTC Rhyme.
You need to have your Exchange ActiveSync account set up on HTC Rhyme first.
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From the Home screen, tap
.
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In the search box, enter the first few letters of the contact's name or email address.
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Tap
.
Under Company contacts, matching names are listed.
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Tap the name of the contact you want copied on HTC Rhyme, and then tap Save to People.